[Download] "Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene" by Ruijun Hou * Book PDF Kindle ePub Free
eBook details
- Title: Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
- Author : Ruijun Hou
- Release Date : January 05, 2017
- Genre: Chemistry,Books,Science & Nature,
- Pages : * pages
- Size : 3595 KB
Description
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<